Electrochemical energy storage with redox flow batteries (RFBs) under subzero temperature is of great significance for utilizing renewable energy in cold regions. However, RFBs are generally ...
Rechargeable calcium batteries (RCB) are prospective candidates for sustainable energy storage, as they hold the promise of the high energy density of lithium ion batteries (LIBs) while simultaneously combining it with highly abundant raw materials. However, for long time, calcium batteries have faced severe issues with regard to cycling …
An ambipolar PEDOT-perfluorinated porphyrin electropolymer: application as an active material in energy storage systems† Elizabeth Bermúdez Prieto‡ a, Edwin J. González López‡ b, Claudia A. Solis‡ a, Jhair C. Leon Jaramillo‡ a, Lorena P. Macor a, Rodrigo E. Domínguez c, Yohana B. Palacios b, Silvestre Bongiovanni Abel d, Edgardo …
Lithium–sulphur batteries attract increasing interest due to their high theoretical specific capacity, advantageous economy, and "eco-friendliness". In this study, a metal–organic framework (MOF) GaTCPP containing a porphyrinic base ligand was used as a conductive additive for sulphur. GaTCPP was synthesized, chara
The novel functionalized porphyrin [5,15-bis (ethynyl)-10,20-diphenylporphinato]copper (II) (CuDEPP) was used as electrodes for rechargeable energy-storage systems with an extraordinary combination of storage capacity, rate capability, and cycling stability. The ability of CuDEPP to serve as an electron donor or acceptor …
The development of functional organic materials is crucial for the advancement of various fields, such as optoelectronics, energy storage, sensing, and biomedicine. In this context, we successfully prepared a stable ambipolar perfluoroporphyrin-based polymeric film by electrochemical synthesis. Our strategy involve
Compared to pure graphdiyne, the porphyrins played an important role in the composition and the structure of the two composite materials, which can be seen by energy dispersive spectrum elemental mapping in Fig. 2 d–e and i–j.
In this work, they proposed copper(II)[5,15-bis-(ethynyl)−10,20-diphenylporphinato]porphyrin (CuDEPP) as a self-conditioned electrode material for …
The ability of the porphyrin complex to serve as an electron donor or acceptor is advantageous for various energy-storage applications (see picture). Abstract The novel functionalized porphyrin [5,15-bis(ethynyl)-10,20-diphenylporphinato]copper(II) (CuDEPP) was used as electrodes for rechargeable energy-storage systems with an …
Covalent organic frameworks (COFs) represent an emerging class of porous crystalline materials and have recently shown interesting applications in energy storage. Herein, we report the construction of a cycle-stable sulfur electrode by embedding sulfur into a 2D COF. The designed porphyrin-based COF (Por-COF), featuring a …
Abstract and Figures. We report the use of a novel functionalized porphyrin of [5,15-Bis (ethynyl)-10,20-diphenylporphinato]copper (II) (CuDEPP) as electrodes for rechargeable batteries with ...
The flexible, sustainable, and environmentally friendly nature of bipolar redox organics has generated significant interest in their utilization as electrode materials for energy storage. In this perspective, a novel copper(II)[5,15-bis(ethynyl)-10,20-di ferrocenyl porphinato] – (CuDEFcP) has been developed and employed as electrodes in …
This study explores the electrochemical performance of porphyrin active materials in calcium batteries and represents a significant step forward in the progress toward organic electrodes for multivalent …
Recently, porphyrin-based materials have attracted considerable interest as a new class of organic electrode materials for electrochemical energy storage. 10 As previously shown, 10k the …
This paper mainly takes the ingenious utilization of porphyrin derivatives in perovskite solar cells, dye-sensitized solar cells, and lithium batteries as the background to review the …
Energy Storage Materials Volume 22, November 2019, Pages 40-47 Hierarchical assemblies of conjugated ultrathin COF nanosheets for high-sulfur-loading and long-lifespan lithium–sulfur batteries: Fully-exposed porphyrin matters
Request PDF | Porphyrin complex as self-conditioned electrode material for high performance energy storage | We report the use of a novel functionalized porphyrin of [5,15-Bis(ethynyl)-10,20 ...
This study explores the electrochemical performance of porphyrin active materials in calcium batteries and represents a significant step forward in the progress …
An ambipolar PEDOT-perfluorinated porphyrin electropolymer: application as an active material in energy storage systems† Elizabeth Bermúdez Prieto‡ a, Edwin J. González López‡ b, Claudia A. Solis‡ a, Jhair C. Leon Jaramillo‡ a, Lorena P. Macor a, Rodrigo E. Domínguez c, Yohana B. Palacios b, Silvestre Bongiovanni Abel d, Edgardo N. Durantini …
Herein, a bipolar organic molecule combining both porphyrin and ferrocene moieties (CuDEFcP) [5,15-bis(ethynyl)-10,20-di ferrocenyl porphinato]copper(II)) has been developed. It is proposed as a new organic electrode material with multifunctional application for rechargeable organic lithium-based batteries (ROLBs) and dual-ion organic symmetric …
Porphyrin-based framework materials for energy conversion. Jiawei Gu1,Yi Peng1,Ting Zhou1,Jiao Ma1, Huan Pang 1( ), Yusuke Yamauchi 2( ) 1 Country School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225009, China. 2 Australian Institute for Bioengineering and Nanotechnology (AIBN) and School of Chemical Engineering, The ...
Dr. Ebrahim Abouzari-Lotf Helmholtz Institute Ulm (HIU) Electrochemical Energy Storage, Helmholtzstraße 11, 89081 Ulm, Germany Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz …
Electrochemical energy storage with redox-flow batteries (RFBs) under subzero temperature is of great significance for the use of renewable energy in cold …
An ambipolar PEDOT-perfluorinated porphyrin electropolymer: application as an active material in energy storage systems† Elizabeth Bermudez Prieto,´ ‡a Edwin J. Gonz´alez L opez,´ ‡b Claudia A. Solis, ‡a Jhair C. Leon Jaramillo,‡a Lorena P. Macor, a Rodrigo E. Dom´ınguez,c ...
Organic batteries are regarded as promising candidates for the future gen-eration electrochemical energy storage due to their low-cost, recyclability, resource sustainability, environmental friendliness, structural diversity, and flexibility. Herein, we report on the novel porphyrin-based. 1. Introduction electrode materials extending their use ...
The novel functionalized porphyrin [5,15-bis (ethynyl)-10,20-diphenylporphinato]copper (II) (CuDEPP) was used as electrodes for rechargeable energy-storage systems with an extraordinary combination of storage capacity, rate capability, …
Auto‐Oxygenated Porphyrin‐Derived Redox Mediators for High‐Performance Lithium Air‐Breathing Batteries. Because of their distinct energy potentials, Li air‐breathing batteries have been highlighted as promising energy storage systems; however, the sluggish oxygen reduction and evolution reactions (ORR….
These unique structural features make the porphyrin-based COFs an attractive material for energy storage. 2.2 Porphyrin-Based COF Materials for Lithium Storage The first 2D COF used as an anode for lithium-ion batteries has been reported, 9 in which a high ...